Edward Frankland first reported the compound in 1848 from zinc and ethyl iodide, the first organozinc compound discovered. He improved the synthesis by using diethyl mercury as starting material The contemporary synthesis consists of the reaction of a 1:1 mixture of ethyl iodide and ethyl bromide with a zinc-copper couple, a source of reactive zinc.
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Dithiocarbamate salts are pale colored solids that are soluble in water and polar organic solvents. Reactions. Dithiocarbamates are readily S-alkylated. Thus, methyl dimethyldithiocarbamate can be prepared by methylation of the dithiocarbamate: (CH 3) 2 NCS 2 Na + (CH 3 O) 2 SO 2 → (CH 3) 2 NC(S)SCH 3 + Na[CH 3 OSO 3]
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ZINC DIETHYLDITHIOCARBAMATE. The number of sulfur atoms in the sulfur bridges varies physical properties of the end products. Short bridges containing one or two sulfur atoms offer heat resistance and long bridges offer flexible property. Vulcanization can also be accomplished with certain peroxides, gamma radiation,.
Other vulcanizing agents include amine compounds for the cross-linking of fluorocarbon rubbers, metal oxides for chlorine-containing rubbers (notably zinc oxide for chloroprene rubber) and phenol-formaldehyde resins for the production of heat-resistant butyl rubber vulcanizates.
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Zinc dimethyldithiocarbamate 97% Synonym: Dimethyldithiocarbamic acid zinc salt, Ziram CAS Number 137-30-4. Linear Formula (CH 3) 2 NCSSZnSCSN(CH 3) 2. Molecular Weight 305.82 . Beilstein/REAXYS Number 3707008 . EC Number 205-288-3. MDL number MFCD00064797. PubChem Substance ID …
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